Product ID:PROMAR 200 LATEX INTERIOR FINISH, EG-SHEL, BASE Y, B20 W 202
MSDS Date:03/20/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLCMR

THE SHERWIN-WILLIAMS CO.

101 PROSPECT AVE. N.W.
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 1NE25

SHERWIN-WILLIAMS CO

CLEVELAND, OH 44115 US

Telephone: 216-566-2902

Cage: 1NE25

0.1 MMHG.)

CAS: 107-21-1

RTECS: KW2975000

OSHA PEL 50 PPM

ACGIH TLV: C 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 10 MG/M3 (AS DUST)

ACGIH TLV: 10 MG/M3 (AS DUST)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

WATER

CAS: 7732-18-5

RTECS: ZC0110000

CRISTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

OSHA PEL see Table Z-3

ACGIH TLV: 0.05 MG/M3

KAOLIN

CAS: 1332-58-7

RTECS: GF1670500

OSHA PEL 5 MG/M3

ACGIH TLV: 2 MG/M3

0.1 MMHG)

CAS: 112-34-5

RTECS: KJ9100000

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ROUTES OF EXPOSURE: EXPOSURE MAY BE BY
INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF
USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION, & PERSONAL PROTE CTIVE EQUIPMENT. ACUTE: IRRITATION OF
EYES, SKIN & UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN
HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS.
CHRONIC: CRYSTALLINE SILICA (QUART Z, CRISTOBALITE) IS LISTED BY
IARC & NTP. LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH
CAN OCCUR ONLY WHEN SANDING OR ABRADING THE DRY FILM, MAY CAUSE
LUNG DAMAGE (SILICOSIS) & POSSIBLY CAN CER. (EFFECTS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:CARBON BLACK: IARC GROUP 2B, VOLUME 65,
PAGE 149, 1996. QUARTZ, SILICA, CRYSTALLINE (RESPIRABLE SIZE): NTP
9TH REPORT, KNOWN TO BE HUMAN CARCINOGEN; SILICA, CRYSTALLINE
(INHALED IN THE FORM OF QUARTZ OR CRISTOBALITE FROM OCCUPATION
SOURCES): IARC GROUP 1, VOL 68, PAGE 41, 1997.
Effects of Overexposure:HEALTH HAZARDS (CONT'D): CARBON BLACK IS
CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B)
BASED ON EXPERIMENTAL ANIMAL DATA, HOWEVER, THERE IS INSUFFICIENT
EVIDENCE IN HUMANS FOR ITS C ARCINOGENICITY. ETHYLENE GLYCOL IS
CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH
DEFECTS IN RATS AND MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER
OR BY GAVAGE. THERE IS NO EVIDEN CE TO INDICATE IT CAUSES BIRTH
DEFECTS IN HUMANS. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS
MAY CAUSE ADVERSE EFFCTS TO LIVER & URINARY SYSTEMS. RATS EXPOSED
TO TITANIUM DUST (TOXICOLOGICAL)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: GET
MEDICAL ATTENTION.

Flash Point:NONE
Lower Limits:N.AP.
Upper Limits:N.AP.
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING NIOSH
APPROVED SELF CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED
TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. FLAMMABILITY
CLASSIFICATION: NOT APPLICABLE.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:DOL STORAGE CATEGORY: NOT APPLICABLE.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. USE ONLY WITH
ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY (OTHER
PRECAUTIONS)
Other Precautions:HANDLING/STORAGE (CONT'D): MIST. AVOID CONTACT WITH
SKIN AND EYES. WASH HANDS AFTER USING.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN THE INGREDIENTS SECTION. WHEN SANDING OR
ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY
NIOSH FOR DUST WHICH MAY BE GENERATED (HYGIENE PRACT)
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN INGREDIENTS SECTION IS MAINTAINED BELOW
APPLICABLE (OTHER PROT EQUIP)
Protective Gloves:WEAR IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES . WEAR SAFETY
(WORK HYGIENE)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . VENTILATION (CONT'D): EXPOSURE LIMITS. REFER TO
OSHA STANDARDS 1910.94, 1910.107, 1910.108.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH HANDS AFTER USING. RESPIRATORY PROT (CONT'D): FROM THIS
PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE. EYE PROT: SPECTACLES
WITH UNPERFORATED SIDESHIELDS.
Supplemental Safety and Health
THESE COATINGS MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE
PARTICULATES (LISTED "AS DUST" IN INGREDIENTS SECTION) WHICH MAY
BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING OR ABRADING OF
THE DRIE D FILM. IF NO SPECIFIC DUSTS ARE LISTED IN INGREDIENTS
SECTION, THE APPLICABLE LIMITS FOR NUISANCE DUSTS (TOX INFO)

Boiling Pt:=100.C, 212.F
B.P. Text:RANGE: 212 - 477F.
Melt/Freeze Pt:M.P/F.P Text:N.A.
Vapor Density:> THAN AIR
Spec Gravity:1.13 - 1.50
pH:9.0 - 9.5
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:N.A.
Appearance and Odor:NOT SPECIFIED BY MANUFACTURER .
Percent Volatiles by Volume:56-80%

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN. PHOTOCHEMICALLY REACTIVE: NO.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODUCTS IS NOT HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING POLLUTION.

Toxicological Information:N/P. SIGNS/SYMPTOMS OF OVEREXPOSURE (CONT'D):
AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS
ARE NOT ATTAINABLE IN THE WORKPLACE. REDNESS AND ITCHING OR BURNING
SENSATION MAY INDICA TE EYE OR EXCESSIVE SKIN EXPOSURE.
SUPPLEMENTAL SAFETY (CONT'D): ARE ACGIH TLV 10 MG/M3 (TOTAL DUST),
3 MG/M3 (RESPIRABLE FRACTION), OSHA PEL 15 MG/M3 (TOTAL DUST), 5
MG/M3 (RESPIRABLE FRACTION).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:N/P.

Transport Information:N/P.

SARA Title III Information:INGREDIENTS SUBJECT OT THE REPORTING
REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) SECTION 313, 40 CFR 372.65C: 2-(2-BUTOXYETHOXY) ETHANOL AND
ETHYLENE GLYCOL.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:THIS PRODUCT CONTAINS CHEMICALS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER.